Variation of Molar Conductivity With Concentration

IMPORTANT

Variation of Molar Conductivity With Concentration: Overview

This topic shows the dependency of conductivity on the concentration of strong and weak electrolytes while diluting the solution. It also explains the conductance behavior of strong and weak electrolytes.

Important Questions on Variation of Molar Conductivity With Concentration

MEDIUM
IMPORTANT

Determine the degree of ionization and pH of a 0.05 M of ammonia solution. The ionization constant of ammonia is 1.77 × 10-5.

EASY
IMPORTANT

The molar conductivity of a solution at infinite dilution is known as _____ molar conductivity.

EASY
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The dissociation of a weak electrolyte increases on dilution.

EASY
IMPORTANT

In the relationship, λc=λ-BC, the equivalent conductance of NaCl at concentration C related with the equivalent conductance at _____.

EASY
IMPORTANT

Conductivity of a solution decreases with dilution, whereas molar conductivity increases with dilution.

EASY
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Dilution increases the conductivity of the weak electrolyte. How does the conductivity of ionic solution measured?

EASY
IMPORTANT

The dissociation constant is inversely proportional to the square root of its concentration. Prove it.

EASY
IMPORTANT

How does the dilution affect the conductivity of the strong electrolytes?

EASY
IMPORTANT

Express the effect of dilution on molar conductivity of the strong electrolyte.

MEDIUM
IMPORTANT

Molar conductivity of ionic solution depends on _____.(temperature/distance between electrodes)

MEDIUM
IMPORTANT

Molar conductivity of ionic solution depends on _____.

HARD
IMPORTANT

How does the variation in molar conductivity of an electrolyte with concentration differs for strong and weak electrolytes?

HARD
IMPORTANT

How does molar conductivity of an electrolyte vary with concentration?

EASY
IMPORTANT

The constant 'A' in the equation  λm0=λm+AC is depends on- 

HARD
IMPORTANT

Given,

λ of 0.01 M MgCl2 is 220 S cm2 mol-1

λ° of MgCl2 is 240 S cm2 mol-1

λ° of Mg2+ is 100 S cm2 mol-1

All above measurements are done in an electrolytic cell. Assuming MgCl2 to be a strong electrolyte which of the following is/are incorrect?

HARD
IMPORTANT

Equivalent conductance of 1M CH3COOH is 10 ohm-1 cm2 equiv-1 and that at infinite dilution is 200 ohm-1 cm2, equiv-1. Hence % ionisation of CH3COOH is :

EASY
IMPORTANT

For strong electrolytes the plot of molar conductance vsC is

EASY
IMPORTANT

The pH of 0.005 M acid solution. What is the percentage ionization of the acid?

MEDIUM
IMPORTANT

The equivalent conductance of NaCl at concentration C and at infinite dilution are λ C and λ , respectively. The correct relationship between λ C and λ is given as :
(where the constant B is positive)

EASY
IMPORTANT

Conductivity of 0.00241 M acetic acid is 7.896 x 10-5 S cm-1 
Calculate its molar conductivity. If Λ m o for acetic acid is 390.5 S cm2 mol-1, what is its dissociation constant ?